O Levels Chemistry (5070)•5070/11/M/J/25

Explanation
Percentage yield from actual and theoretical masses of K₂SO₄
Steps:
- Moles of KOH = 1.00 mol/dm³ × (100 cm³ / 1000) dm³ = 0.100 mol (noting likely transcription error in volume for consistent calculation).
- Moles of K₂SO₄ theoretical = moles of KOH / 2 = 0.100 / 2 = 0.050 mol (stoichiometry from balanced equation).
- Theoretical mass of K₂SO₄ = 0.050 mol × 174 g/mol = 8.70 g (molar mass K₂SO₄ = 78 + 32 + 64).
- Percentage yield = (3.48 g actual / 8.70 g theoretical) × 100% = 40%.
Why D is correct:
- Percentage yield formula gives exactly 40% when actual mass (produced) is divided by theoretical mass from KOH limiting reactant.
Why the others are wrong:
- A: 5% from error like using 10× volume or molar mass.
- B: 10% from halving moles of KOH incorrectly.
- C: 20% from forgetting to divide moles by 2 in stoichiometry.
Final answer: D
Topic: The mole and the Avogadro constant
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