O Levels Chemistry (5070)•5070/11/M/J/24

Explanation
Reverse Connections for Cathode Plating
Steps:
- In electroplating, copper ions from CuSO4 solution reduce and deposit on the cathode.
- The steel key must be the cathode to attract Cu2+ ions for coating.
- If connections are reversed, the key acts as anode, oxidizing instead of plating.
- Reversing connections makes the key the cathode, enabling deposition.
Why D is correct:
- The cathode is the negative electrode where reduction occurs, per Faraday's laws of electrolysis, depositing Cu atoms on the key.
Why the others are wrong:
- A: Higher concentration increases plating rate but doesn't fix incorrect polarity.
- B: Dilute sulfuric acid lacks Cu2+ ions needed for copper plating.
- C: Identical to D, but listed separately; no unique correction.
Final answer: D
Topic: Electrolysis
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