O Levels Chemistry (5070)•5070/12/M/J/23

Explanation
Lime's Dual Effect on Soil pH and Fertilizer Availability
Steps:
- Calcium hydroxide (Ca(OH)₂) dissociates to release OH⁻ ions, neutralizing H⁺ in acidic soil via Ca(OH)₂ + 2H⁺ → Ca²⁺ + 2H₂O (equation 2).
- This raises soil pH, reducing acidity as intended.
- At higher pH, ammonium fertilizers (NH₄⁺) convert to volatile NH₃ gas via 2NH₄⁺ + Ca(OH)₂ → Ca²⁺ + 2NH₃↑ + 2H₂O (equation 3), causing nitrogen loss.
- Equations 2 and 3 together explain both the acidity reduction and fertilizer inefficiency.
Why C is correct:
- Option C pairs equation 2 (pH neutralization) with equation 3 (ammonia volatilization from fertilizers), directly linking lime's benefits and drawbacks per acid-base chemistry principles.
Why the others are wrong:
- A includes irrelevant equations not tied to pH or nutrient loss.
- B mixes neutralization with unrelated phosphate precipitation, missing nitrogen loss.
- D focuses only on precipitation reactions, ignoring acidity reduction.
Final answer: C
Topic: Fertilisers
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