O Levels Chemistry (5070)•5070/12/M/J/23

Explanation
Higher acid concentration speeds up the reaction and increases total gas yield Steps:
- Compare data: Experiment 2 shows faster initial gas production (30 cm³ vs. 20 cm³ at 20 s) and higher volume at 60 s (75 cm³ vs. 60 cm³), with rate slowing to match experiment 1 later.
- Reaction rate depends on [HCl] and CaCO₃ surface area; total CO₂ volume equals moles of acid (excess CaCO₃).
- Faster rate and higher volume at fixed time indicate increased [HCl], raising both rate and total yield.
- Other changes either match rate (A) or increase rate without raising total yield (C, D).
Why B is correct:
- Higher [HCl] increases collision frequency (collision theory), accelerating rate; same 100 cm³ volume means more moles, yielding more CO₂.
Why the others are wrong:
- A: Same [HCl] keeps initial rate unchanged, though total yield rises; data shows faster rate.
- C: Greater surface area speeds rate but total yield unchanged (same acid moles).
- D: Higher temperature boosts rate (Arrhenius equation) but total yield unchanged.
Final answer: B
Topic: Rate of reaction
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