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O Levels Chemistry (5070)•5070/12/M/J/23
Question 16 from 5070/12/M/J/23

Explanation

Higher acid concentration speeds up the reaction and increases total gas yield Steps:

  • Compare data: Experiment 2 shows faster initial gas production (30 cm³ vs. 20 cm³ at 20 s) and higher volume at 60 s (75 cm³ vs. 60 cm³), with rate slowing to match experiment 1 later.
  • Reaction rate depends on [HCl] and CaCO₃ surface area; total CO₂ volume equals moles of acid (excess CaCO₃).
  • Faster rate and higher volume at fixed time indicate increased [HCl], raising both rate and total yield.
  • Other changes either match rate (A) or increase rate without raising total yield (C, D).

Why B is correct:

  • Higher [HCl] increases collision frequency (collision theory), accelerating rate; same 100 cm³ volume means more moles, yielding more CO₂.

Why the others are wrong:

  • A: Same [HCl] keeps initial rate unchanged, though total yield rises; data shows faster rate.
  • C: Greater surface area speeds rate but total yield unchanged (same acid moles).
  • D: Higher temperature boosts rate (Arrhenius equation) but total yield unchanged.

Final answer: B

Topic: Rate of reaction

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