O Levels Chemistry (5070)•5070/12/M/J/22

Explanation
Naphtha to propanol via cracking and hydration
Steps:
- Naphtha fraction contains C5-C10 alkanes from crude oil.
- Process X cracks these alkanes into smaller alkenes like propene.
- Process Y hydrates propene with steam to form propanol (CH3CH=CH2 + H2O → CH3CH(OH)CH3).
- This sequence matches industrial production of alcohols from petroleum.
Why A is correct:
- Cracking (X) produces alkenes from naphtha; reaction with steam (Y) adds water across the double bond per Markovnikov's rule, yielding propanol.
Why the others are wrong:
- B: Fermentation produces bio-alcohols like ethanol from sugars, not petroleum alkenes.
- C: Fractional distillation separates naphtha but doesn't convert it; cracking is needed next.
- D: Fractional distillation is prior to naphtha isolation; fermentation is biological, irrelevant to petroleum.
Final answer: A
Topic: Fuels
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