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O Levels Chemistry (5070)•5070/12/M/J/22
Question 35 from 5070/12/M/J/22

Explanation

Naphtha to propanol via cracking and hydration

Steps:

  • Naphtha fraction contains C5-C10 alkanes from crude oil.
  • Process X cracks these alkanes into smaller alkenes like propene.
  • Process Y hydrates propene with steam to form propanol (CH3CH=CH2 + H2O → CH3CH(OH)CH3).
  • This sequence matches industrial production of alcohols from petroleum.

Why A is correct:

  • Cracking (X) produces alkenes from naphtha; reaction with steam (Y) adds water across the double bond per Markovnikov's rule, yielding propanol.

Why the others are wrong:

  • B: Fermentation produces bio-alcohols like ethanol from sugars, not petroleum alkenes.
  • C: Fractional distillation separates naphtha but doesn't convert it; cracking is needed next.
  • D: Fractional distillation is prior to naphtha isolation; fermentation is biological, irrelevant to petroleum.

Final answer: A

Topic: Fuels

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