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O Levels Chemistry (5070)•5070/12/M/J/21
Question 34 from 5070/12/M/J/21

Explanation

Aluminium's Extraction and Reactivity Properties

Steps:

  • Evaluate extraction: Aluminium is extracted via electrolysis of Al2O3 in molten cryolite, not by heating with carbon.
  • Identify production site: In electrolysis, Al metal forms at the cathode, while oxygen gas forms at the anode.
  • Assess reactivity: Aluminium appears unreactive due to a protective oxide layer (Al2O3) that prevents further reaction.
  • Examine uses: Aluminium's low density and good conductivity make it ideal for overhead cables, not high density.

Why C is correct:

  • Aluminium forms a thin, impermeable Al2O3 coating via 4Al + 3O2 → 2Al2O3, passivating the metal and reducing reactivity despite its position in the reactivity series.

Why the others are wrong:

  • A: Heating Al2O3 with carbon does not reduce it to aluminium; carbon reduces less stable oxides like iron(III) oxide.
  • B: Aluminium deposits at the cathode during electrolysis; the anode produces oxygen gas.
  • D: Aluminium has low density (2.7 g/cm³), aiding its use in lightweight cables despite good conductivity.

Final answer: C

Topic: Extraction of metals

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