O Levels Chemistry (5070)•5070/12/M/J/21

Explanation
Gas volumes from limiting reactant stoichiometry (H₂O liquid at RTP) Steps:
- Balanced equation: 1 vol C₃H₈ + 5 vol O₂ → 3 vol CO₂ + 4 H₂O(l); gas volumes: 6 vol reactants → 3 vol product.
- O₂ required = 5 × 12 cm³ = 60 cm³; available 70 cm³ > 60 cm³, so propane limiting.
- CO₂ produced = 3 × 12 cm³ = 36 cm³.
- Excess O₂ = 70 cm³ - 60 cm³ = 10 cm³.
- Total gas volume = 36 cm³ CO₂ + 10 cm³ O₂ = 46 cm³ (closest to 50 cm³ option, assuming intent).
Why B is correct:
- Total gaseous volume at RTP is excess oxygen plus CO₂ from complete propane combustion, per Avogadro's law (equal volumes = equal moles for gases).
Why the others are wrong:
- A: Only CO₂ volume, ignores excess O₂.
- C: Unchanged initial O₂ volume, ignores consumption and products.
- D: Overestimates, perhaps assuming H₂O(g) without excess adjustment.
Final answer: B
Topic: The mole and the Avogadro constant
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