O Levels Chemistry (5070)•5070/11/M/J/21

Explanation
Anode reaction in electrolysis with copper electrodes Steps:
- Anode is the positive electrode where oxidation occurs during electrolysis.
- Pure copper electrodes mean the anode material (Cu) can oxidize to Cu²⁺.
- Possible oxidations include Cu to Cu²⁺ (E°_ox = +0.34 V) or H₂O to O₂ (E°_ox = +1.23 V).
- Cu oxidizes preferentially as it requires less energy than water.
Why B is correct:
- It shows oxidation of the copper anode: Cu → Cu²⁺ + 2e⁻, per standard electrode potential rules.
Why the others are wrong:
- A: Describes reduction of Cu²⁺ to Cu, which happens at the cathode.
- C: Shows reduction of Ag⁺ to Ag, a cathode process.
- D: Indicates oxidation of Ag to Ag⁺, but no Ag metal is present at the anode.
Final answer: B
Topic: Electrolysis
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