O Levels Chemistry (5070)•5070/12/M/J/20

Explanation
Electroplating setup for copper deposition
Steps:
- Identify the goal: deposit copper ions onto steel key via reduction at cathode.
- Select electrolyte with copper ions: aqueous copper(II) sulfate provides Cu²⁺.
- Choose anode: pure copper dissolves to replenish Cu²⁺ ions.
- Assign electrodes: steel key as cathode (negative) for deposition; copper as anode (positive).
Why A is correct:
- Steel key as negative electrode (cathode) allows Cu²⁺ reduction (Cu²⁺ + 2e⁻ → Cu) to plate copper onto it.
Why the others are wrong:
- B: Lacks electrode polarity; steel key not specified as cathode, preventing controlled deposition.
- C: Dilute sulfuric acid has no Cu²⁺ ions, so no copper plating occurs.
- D: Dilute sulfuric acid lacks Cu²⁺; pure copper as cathode would deposit nothing useful on steel key.
Final answer: A
Topic: Electrolysis
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