O Levels Chemistry (5070)•5070/11/M/J/20

Explanation
Polymerisation of ethene uses addition reactions
Steps:
- Identify ethene as an alkene with a C=C double bond that can open for chain formation.
- Recall polymerisation joins monomers into polymers; for ethene, it forms polyethene.
- Determine the reaction type: no small molecules are lost, so it's addition, not condensation.
- Confirm by the general equation: n CH₂=CH₂ → (-CH₂-CH₂-)ₙ.
Why A is correct:
- Addition reactions involve alkenes like ethene adding across the double bond to form polymers without by-products, as in the initiation by free radicals.
Why the others are wrong:
- B: Condensation involves eliminating water or similar from monomers like diols and dicarboxylic acids.
- C: Cracking thermally decomposes large alkanes into smaller alkenes and alkanes.
- D: Esterification reacts carboxylic acids with alcohols to form esters and water.
Final answer: A
Topic: Polymers
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