O Levels Chemistry (5070)•5070/11/M/J/20

Explanation
Rusting requires O₂ and H₂O; magnesium sacrifices to protect iron
Steps:
- Rusting is oxidation of iron needing both oxygen and water for electrochemical reaction.
- Sacrificial protection uses a more reactive metal like magnesium, which corrodes preferentially.
- Check options: conditions must include O₂ + H₂O, and metal must be more reactive than iron.
- Option D matches both criteria.
Why D is correct:
- Rusting follows 4Fe + 3O₂ + 6H₂O → 4Fe(OH)₃, requiring O₂ and H₂O; magnesium, above iron in reactivity series, acts as anode in galvanic cell, oxidizing instead (Mg → Mg²⁺ + 2e⁻).
Why the others are wrong:
- A: O₂ alone insufficient without H₂O; copper below iron in reactivity series, cannot sacrifice.
- B: O₂ alone insufficient; magnesium correct for protection but conditions incomplete.
- C: H₂O alone insufficient without O₂; copper cannot provide sacrificial protection.
Final answer: D
Topic: Corrosion of metals
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