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O Levels Chemistry (5070)•5070/11/M/J/19
Question 14 from 5070/11/M/J/19

Explanation

Electrolytic Refining of Impure Copper

Steps:

  • Set up electrolysis with impure copper as anode, pure copper as cathode, and copper(II) sulfate electrolyte.
  • Apply current: anode oxidizes, releasing Cu²⁺ ions into solution; impurities form sludge.
  • Cu²⁺ ions migrate to cathode and reduce to deposit pure copper.
  • Monitor electrolyte color change to assess process completion.

Why B is correct:

  • Cu²⁺ ions from anode dissolution deposit on cathode, reducing electrolyte concentration per Faraday's laws of electrolysis, fading the blue color.

Why the others are wrong:

  • A: Impure copper anode is used to dissolve and purify, not pure.
  • C: Duplicate of B; not a distinct option.
  • D: Electrolyte is copper(II) sulfate in dilute sulfuric acid, as copper oxide is insoluble in water.

Final answer: B

Topic: Electrolysis

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