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O Levels Chemistry (5070)•5070/12/M/J/18
Question 39 from 5070/12/M/J/18

Explanation

Compound J is a carboxylic acid identified by its reactions

Steps:

  • Reaction with sodium carbonate producing CO2 shows J is an acid that liberates CO2 from carbonates, characteristic of carboxylic acids.
  • Reaction with ethanol yielding a sweet-smelling liquid indicates esterification, where J (as acid) reacts with alcohol to form an ester.
  • Reaction with sodium hydroxide producing a salt confirms neutralization, typical for acids forming carboxylate salts.
  • Matching properties to ethanoic acid, a common carboxylic acid fitting all reactions.

Why A is correct:

  • Ethanoic acid (CH3COOH) reacts with Na2CO3 to give CO2 (2CH3COOH + Na2CO3 → 2CH3COONa + H2O + CO2), with C2H5OH to form ethyl ethanoate (sweet ester), and with NaOH to form sodium ethanoate salt.

Why the others are wrong:

  • B. Ethanol (alcohol) does not react with Na2CO3 to produce CO2.
  • C. Ethyl ethanoate (ester) is neutral and does not liberate CO2 from carbonates.
  • D. Ethyl methanoate (ester) lacks acidic properties to react with Na2CO3 for CO2.

Final answer: A

Topic: Carboxylic acids

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