O Levels Chemistry (5070)•5070/11/M/J/18

Explanation
Reduction of haematite by carbon monoxide in iron extraction
Steps:
- Hot air blasts into furnace, burning coke to form carbon monoxide (CO).
- CO acts as reducing agent, reacting with haematite (Fe₂O₃) to produce iron: Fe₂O₃ + 3CO → 2Fe + 3CO₂.
- Limestone (CaCO₃) decomposes to CaO, which removes silica impurities as slag.
- Molten iron sinks and is tapped off, separating from slag.
Why B is correct:
- Haematite reduction by CO is the core reaction yielding iron, per the blast furnace process equation Fe₂O₃ + 3CO → 2Fe + 3CO₂.
Why the others are wrong:
- A: Calcium carbonate removes impurities via slag formation, but it's a supporting step, not the iron-producing process.
- C: Haematite is reduced, not oxidised; CO₂ is a byproduct, not an oxidising agent.
- D: Haematite requires reduction, not thermal decomposition, which wouldn't yield iron.
Final answer: B
Topic: Extraction of metals
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