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O Levels Chemistry (5070)•5070/11/M/J/18
Question 32 from 5070/11/M/J/18

Explanation

Reduction of haematite by carbon monoxide in iron extraction

Steps:

  • Hot air blasts into furnace, burning coke to form carbon monoxide (CO).
  • CO acts as reducing agent, reacting with haematite (Fe₂O₃) to produce iron: Fe₂O₃ + 3CO → 2Fe + 3CO₂.
  • Limestone (CaCO₃) decomposes to CaO, which removes silica impurities as slag.
  • Molten iron sinks and is tapped off, separating from slag.

Why B is correct:

  • Haematite reduction by CO is the core reaction yielding iron, per the blast furnace process equation Fe₂O₃ + 3CO → 2Fe + 3CO₂.

Why the others are wrong:

  • A: Calcium carbonate removes impurities via slag formation, but it's a supporting step, not the iron-producing process.
  • C: Haematite is reduced, not oxidised; CO₂ is a byproduct, not an oxidising agent.
  • D: Haematite requires reduction, not thermal decomposition, which wouldn't yield iron.

Final answer: B

Topic: Extraction of metals

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